Reactions Rearrangements And Reagents By Snsanyal Pdf 23l Repack -

4. Beckmann Rearrangement

• Substrate: Ketoximes.
• Reagent: Acid catalysts ($H_2SO_4$, $PCl_5$, etc.).
• Outcome: Conversion to Amides.
• Key Rule: The group anti (opposite) to the leaving hydroxyl group migrates.

• Hydration of alkenes: Markovnikov’s rule (e.g., H₂O/H₂SO₄).
• Halogen addition: e.g., Br₂ in CCl₄ (anti-addition).

📘 What is “Reactions, Rearrangements and Reagents” by S.N. Sanyal?

Published by Bharati Bhawan, this book is a staple for:

This book is a highly-regarded handbook for organic chemistry, particularly popular among students preparing for competitive entrance exams like Amit Book Depot Substrate: Ketoximes